Product ID:AIRCRAFT GREEN ZENTHANE, MIL-C-53039A
MSDS Date:01/23/1992
FSC:8010
NIIN:01-246-0717
MSDS Number: BNWWC

HENTZEN COATINGS INC

6937 W MILL ROAD
MILWAUKEE, WI 53218
US

Emergency Phone: DAY 414-353-4200/NIGHT 800-424-9300

Info Phone: 414-353-4200

Preparer: JANE FREEMAN

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

METHYL ISOBUTYL KETONE (SOLVENT) (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 25.74%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PREPOLYMER OF HEXAMETHYLENE DIISOCYANATE

Fraction By Weight: 30-40%

TITANIUM DIOXIDE (PIGMENT)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 1.0-5.0%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

IRON OXIDE (PIGMENT) (NUISANCE DUST)

CAS: 1332-37-2

RTECS: NO7380000

Fraction By Weight: 10-15%

SILICA (PIGMENT)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 20-30%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

METHYL ISOAMYL KETONE (SOLVENT)

CAS: 110-12-3

RTECS: MP3850000

Fraction By Weight: 1.92%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM; 9293

N-BUTYL ACETATE (SOLVENT) (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1.28%

OSHA PEL 150 PPM/200 PPM STEL

ACGIH TLV: 150 PPM/200 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HEXAMETHYLENE DIISOCYANATE MONOMER

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.05%

OSHA PEL 0.005 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

AROMATIC HYDROCARBONS (MIXTURE OF C8'S-C10'S)

CAS: 64742-95-6

Fraction By Weight: 1.22%

Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:VAPOR/MIST: IRRITATION TO SKIN, EYES,
RESP TRACT. CHRONIC: RESPIRATORY SENSITIZATION. REPEATED/PROLONGED
OVEREXPOSURE TO SOLVENTS ASSOCIATED WITH PERMANENT BRAIN & NERVOUS
SYSTEM DAMAGE, LIVER, KIDNEY DAMAGE. MAY CAUSE LUNG INJURY IF NOT
PROPERLY PROTECTED.
Explanation of Carcinogenicity:IARC HAS LISTED SILICA AS A PROBABLE
HUMAN CARCINOGEN.
Effects of Overexposure:VAPOR/MIST: WATERING EYES, THROAT DRYNESS,
COUGHING, HEADACHE, CHEST TIGHTNESS, BURNING SENSATION. HEADACHE,
DIZZINESS, NAUSEA MAY BE EXPERIENCED AS A RESULT OF EXPOSURE TO
SOLVENTS. CHRONIC: ASTHMA L IKE SYMPTOMS SKIN SENSITIZATION:
ALLERGIC DERMATITIS, RASH, ITCHING, HIVES, SWELLING OF EXTREMITIES.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS, CHEMICAL SENSITIZATION.

First Aid:VAPORS: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM
AND QUIET. NOTIFY A PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH LARGE
AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. TAKE TO A
PHYSICIAN FOR M EDICAL TREATMENT. SKIN: WASH AFFECTED AREAS WITH
SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT A PHYSICIAN.
INGESTION: IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY.

Flash Point Method:TCC
Flash Point:60.0F,15.6C
Autoignition Temp:Autoignition Temp Text:840F
Lower Limits:1.0
Upper Limits:8.2
Extinguishing Media:FOAM, DRY CHEMICAL, CO2.
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/SCBA. DURING
A FIRE, IRRITATING AND HIGHLY TOXIC GASES AND SMOKE ARE PRESENT
FROM DECOMPOSITION/COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard:KEEP CNTNRS CLSD. KEEP FROM HEAT/IGNIT
SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT, BURST WHEN CONTAM W/WATER.
DON'T APPLY TO HOT SRFCS. NEVER WELD, CUT TORCH ON

Spill Release Procedures:EVACUATE NON-ESSENTIAL PERSONNEL. REMOVE IGNIT
SOURCES. VENT AREA. AVOID BREATHING VAPORS. COVER SPILL W/INERT
ABSORBENT. POUR NEUTRALIZER OVER SPILL. ALLOW TO REACT 10 MIN.
COLLECT MAT'L W/NONSPARK T OOLS INTO OPEN CNTNRS, ADD MORE
NEUTRALIZER.
Neutralizing Agent:3-8% CONC AMMONIA, 2% DETERGENT, 90-95% WTR OR
TERGITOL TMN-10 (20%), WTR (80%)

Handling and Storage Precautions:DON'T STORE ABOVE 120F OR BELOW 32F.
STORE LRG QTY IN BLDGS IN COMPLY W/OSHA 1910.106. KEEP FROM IGNIT
SOURCE. KEEP CNTNRS CLSD. PROTECT FROM MOISTR.
Other Precautions:IF MOISTURE ENTERS CNTNR, PRESSURE CAN BUILD, CAN
CAUSE SEALED CNTNR TO PRESSURIZE & BURST. DON'T RESEAL IF CONTAM
SUSPECTED. DON'T INGEST. GROUND CNTNR WHEN POURING. AVOID LIQ FREE
FALL IN EXCESS OF FEW INCHES. USE VENT & RESP EQUIP.

Respiratory Protection:SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS
USED UNLESS BELOW OSHA LIMITS, THEN CHEM CARTRIDGE RESPIRATOR OR
AIRLINE RESPIRATORS REQ'D. THE SAME PRECUATIONS SHOULD BE USED
DURING MIXING OR ANY OPERAT IONS WHERE PAINT FUMES WOULD BE
PRESENT.
Ventilation:PROVIDE GEN DILUT/LOCAL EXHAUST (VOL/PATTRN)TO KEEP CONC
BELOW TLV/PEL(MIXING/APPLIC/CURING AREAS) & REMOVE DECOMP PROD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SFTY EYEWEAR W/SPLASH GUARD/SIDE SHLDS.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN
CONTACT AT A MINIMUM.
Work Hygienic Practices:WASH HANDS AND ANY EXPOSED SKIN THOROUGHLY
BEFORE EATING OR SMOKING. SMOKE IN SMOKING AREAS ONLY.
Supplemental Safety and Health
(UNUSUAL FIRE HZD CONT'D) OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT
(EVEN RESIDUE) CAN IGNITE EXPLOSIVELY. (PRECAUTIONS CONT'D) EMPTIED
CONTAINERS MAY RETAIN HAZARDOUS RESIDUE OR EXPLOSIVE VAPORS. FOL
LOW ALL PRECAUTIONS IN THIS DATA SHEET UNTIL CONTAINER IS
THOROUGHLY CLEANED OR DESTROYED.

HCC:F5
Boiling Pt:B.P. Text:232 TO 418F
Decomp Temp:Decomp Text:400F,204C
Vapor Pres:15.00
Vapor Density:> AIR
Spec Gravity:1.25
Viscosity:65-85 KU
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:REACTS WITH WATER.
Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:48.21

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, GLYCOL ETHERS, AMINES.
Stability Condition to Avoid:WATER CONTAMINATION.
Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, TRACES OF
HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE.

Waste Disposal Methods:DISPOSE IN ACCORDANCE W/LOCAL, STATE AND FEDERAL
REGULATIONS. INCINERATION IS PREFERRED METHOD OF DISPOSAL. EPA
#:D001 IGNITABLE REMOVE CNTNRS TO SAFE PLACE--COVER LOOSELY. WASH
DOWN AREA W/NEUTRALIZI NG AGENT & FLUSH SPILL AREA W/WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.